| 100 | 0 | 120 |
| 下载次数 | 被引频次 | 阅读次数 |
花海盆地位于走廊地区的西北缘,是青藏高原向东北方向扩展至阿拉善板块的前缘区域。近年来,在花海盆地下白垩统中沟组中陆续发现了多个铀异常点,铀成矿机理尚不清晰。文章以花海盆地中沟组砂岩为研究对象,采用X射线荧光光谱仪(XRF)和电感耦合等离子体质谱仪(ICP-MS)分析其地球化学特征,进而探讨砂岩的沉积学特征、物源特征、成岩演化过程。研究结果表明:中沟组砂岩具有较高的成熟度,岩石学及地球化学特征指示其主要物源为中酸性长英质岩浆岩;早期发育于中等分层的富氧-次富氧底层水环境,后期受强烈改造作用影响,形成灰—黄—红色调渐变特征,氧化程度呈现由低到高的演化趋势;U具有从红色砂岩向灰色砂岩迁移的特征,且与Pb、Th、Sn、Ti呈显著正相关;砂岩的稀土元素配分模式呈右倾型,具有中等—弱负Eu异常特征,∑REE含量随砂岩颜色由红色、黄色、灰色向灰黄色、红黄色依次递增,较高的LREE/HREE值及明显的轻重稀土分异特征进一步证实了后生蚀变改造过程。研究结果为深入理解花海盆地中沟组砂岩的成因机制及沉积环境演化提供了重要依据。
Abstract:Huahai Basin is located at the northwest of the corridor area which is the leading edge area where QinghaiTibet Plateau extends northeastward to Alxa Plate. Multiple uranium mineralization anomalies have been discovered in recent years, but the mineralization mechanism remains unclear. In this article, sandstone of Zhonggou Formation in Huahai Basin was studied with X-ray XRF and ICP-MS to analyze its geochemical characteristics, the sedimentary characteristics, source characteristics and diagenetic evolution process of the sandstone. The results show that the sandstone of Zhonggou Formation has a relatively high maturity. The petrological and geochemical characteristics indicated that its main source was moderately acidic feldspar magmatic rock. The sandstone deposited in the moderately stratified oxygen-rich-sub-oxygen-rich bottom water environment at the early stage. Then, affected by the increasing strong transformation effect and formed a gradient characteristic of gray-yellow-red tones. Uranium seems to be migrated from red sandstone to grey sandstone, and presented significantly positive correlation with Pb, Th, Sn and Ti. REE pattern of sandstone is right-leaning with moderate to weak negative Eu anomaly. ∑ REE content increases successively from red, yellow and gray to grayish yellow and red-yellow sandstone. The high LREE/HREE and obvious differentiation characteristics of light and heavy rare earths further confirm the post-metamorphism transformation process. Therefore, this study provides an important basis for an in-depth understanding of the genetic mechanism and sedimentary environment evolution of sandstone in Zhonggou Formation sandstone in Huahai Basin.
陈柏林,刘建生,王春宇,张永双,刘建民,董诚,吴乃芬.2008.阿尔金断裂昌马大坝-宽滩山段全新世活动特征[J].地质学报,82(4):433-440.
程晓敢,郑德文,杨树锋,肖安成,陈汉林. 2006.酒泉盆地晚白垩世—古新世构造特征[J].石油与天然气地质,27(4):522-527.
冯绍南,严兆彬,张文文,吴修俣. 2024.松辽盆地南部开鲁坳陷姚家组砂岩物源示踪研究:来自岩石地球化学及锆石U-Pb年代学的制约[J].铀矿地质,40(4):633-647.
龚建业,张志诚,张臣,郭召杰,王晓丰. 2007.阿尔金断裂带东端断裂展布型式的研究[J].北京大学学报(自然科学版),43(2):169-175.
郭庆银,陈祖伊,刘红旭,于金水. 2006.北山-走廊地区中-新生代构造演化及盆地产铀远景评价[J].铀矿地质,22(6):321-327.
郭顺,叶凯,陈意,刘景波,张灵敏. 2013.开放地质体系中物质迁移质量平衡计算方法介绍[J].岩石学报,29(5):1486-1498.
贺锋,鲁宝龙,张字龙,牛霆,霍志达,贾翠,杨梦佳. 2019.走廊地区花海盆地砂岩型铀矿成矿条件及找矿潜力分析[J].铀矿地质,35(5):292-299.
贺锋,倪仕琪,牛霆,郭长林,张字龙,田明明. 2021.酒泉盆地砂岩型铀成矿规律及白垩系找矿方向[J].铀矿地质,37(3):377-390.
何光玉,杨树锋,陈汉林,肖安成,程晓敢. 2004.河西走廊西段及邻区早白垩世盆地的重新厘定[J].石油学报,25(6):18-22.
黄世杰. 1994.层间氧化带砂岩型铀矿的形成条件及找矿判据[J].铀矿地质,10(1):6-13.
李奋其,王成善,朱利东,向芳. 2002.区域挤压体制下盆-山耦合关系探讨:以河西走廊和北祁连山为例[J].沉积与特提斯地质,22(4):17-25.
黎彤. 1994.中国陆壳及其沉积层和上陆壳的化学元素丰度[J].地球化学,23(2):140-145.
李钊,余小林,周伟,武杰. 2024.二连盆地脑木更凹陷赛汉组砂岩地球化学特征及沉积环境[J].四川地质学报,44(2):306-311,321.
李卓仑,张乃梦,王乃昂,程弘毅,李育. 2014.晚冰期以来河西走廊花海古湖泊演化过程及其对气候变化的响应[J].中国沙漠,34(2):342-348.
覃素华,王小善,康南昌,贺保卫,白军,庞雪燕,段新红,吴占奎. 2013.阿尔金断裂对酒泉盆地的控制作用分析[J].岩石学报,29(8):2895-2905.
吴德海,夏菲,潘家永,刘国奇,黄国龙,刘文泉,吴建勇.2019.粤北棉花坑铀矿床热液蚀变与物质迁移研究[J].岩石学报,35(9):2745-2764.
熊国庆,王剑,胡仁发. 2008.贵州梵净山地区震旦系微量元素特征及沉积环境[J].地球学报,29(1):51-60.
薛伟,薛春纪,池国祥,彭云彪,王凯. 2010.鄂尔多斯盆地东胜砂岩型铀矿微量和稀土元素地球化学特征[J].现代地质,24(4):776-784.
张健,张海华,陈树旺,郑月娟,张德军,苏飞,黄欣. 2020.松辽盆地北部上二叠统林西组地球化学特征及地质意义[J].吉林大学学报(地球科学版),50(2):518-530.
张进,李锦轶,李彦峰,马宗晋. 2007.阿拉善地块新生代构造作用:兼论阿尔金断裂新生代东向延伸问题[J].地质学报,81(11):1481-1497.
张金带. 2004.我国铀资源潜力概略分析与铀矿地质勘查战略[J].铀矿地质,20(5):260-265.
张培震,闵伟,邓起东,毛凤英. 2003.海原活动断裂带的古地震与强震复发规律[J].中国科学D辑:地球科学,33(8):705-713.
张天福,孙立新,张云,程银行,李艳锋,马海林,鲁超,杨才,郭根万. 2016.鄂尔多斯盆地北缘侏罗纪延安组、直罗组泥岩微量、稀土元素地球化学特征及其古沉积环境意义[J].地质学报,90(12):3454-3472.
张新虎. 2007.甘肃省区域构造及区域成矿找矿研究[D].兰州:兰州大学.
邹小波,史永强,郑悦,石吉勇,胡雪桃,蒋彩萍,黄晓玮,徐艺伟.2018.基于荧光共振能量转移的金纳米粒子/碳量子点荧光纳米探针检测精氨酸[J].分析化学,46(6):960-968.
Bhatia M R,Crook K A W. 1986. Trace element characteristicsof graywackes and tectonic setting discrimination ofsedimentary basins[J]. Contributions to Mineralogy andPetrology,92:181-193.
Boynton W V. 1984. Cosmochemistry of the rare earth elements:meteorite studies[M]//Developments in geochemistry.Amsterdam:Elsevier,2:63-114.
Chen Bailin,Liu Jiansheng,Wang Chunyu,Zhang Yongshuang,LiuJianmin,Dong Cheng,Wu Naifen. 2008. Study on the activityof the Changmadaba-Kuangtanshan segment of eastern AltynTagh fault during Holocene Epoch[J]. Acta Geologica Sinica,82(4):433-440(in Chinese with English abstract).
Cheng Xiaogan,Zheng Dewen,Yang Shufeng,Chen Hanli. 2006.A study on characteristics of the Late Cretaceous-Paleocenestructures in Jiuquan Basin[J]. Oil&Gas Geology,27(4):522-527(in Chinese with English abstract).
Cox R,Lowe D R,Cullers R L. 1995. The influence of sedimentrecycling and basement composition on evolution of mudrockchemistry in the southwestern United States[J]. Geochimicaet Cosmochimica Acta,59(14):2919-2940.
Dypvik H. 1984. Geochemical compositions and depositionalconditions of Upper Jurassic and Lower Cretaceous Yorkshireclays,England[J]. Geological Magazine,121(5):489-504.
Feng Shaonan,Yan Zhaobin,Zhang Wenwen,Wu Xiuyu. 2024.Provenance tracing of Yaojia Formation sandstone in Kailudepression,southern Songliao Basin:Constraints frompetrogeochemistry and zircon U-Pb chronology[J]. UraniumGeology,40(4):633-647(in Chinese with English abstract).
Francois R. 1988. A study on the regulation of the concentrationsof some trace metals(Rb, Sr, Zn, Pb, Cu, V, Cr, Ni, Mnand Mo)in Saanich Inlet sediments,British Columbia,Canada[J]. Marine Geology,83(1-4):285-308.
Gong Jianye,Zhang Zhicheng,Zhang Chen,Guo Zhaojie,WangXiaofeng. 2007. Study of distributing pattern of the easternterminal of the Altyn Tagh fault zones[J]. Acta ScientiarumNaturalium Universitatis Pekinensis,43(2):169-175(inChinese with English abstract).
Grant J A. 1986. The isocon diagram:A simple solution to Gresens’equation for metasomatic alteration[J]. Economic geology,81(8):1976-1982.
Guo Qingyin,Chen Zuyi,Liu Hongxu,Yu Jinshui. 2006. Meso-Cenozoic tectonic evolution and uranium potential evaluationsof basins in Beishan-Gansu Corridor region[J]. UraniumGeology,22(6):321-327(in Chinese with English abstract).
Guo Shun,Ye Kai,Chen Yi,Liu Jingbo,Zhang Lingmin. 2013.Introduction of mass-balance calculation method forcomponent transfer during the opening of a geological system[J]. Acta Petrologica Sinica,29(5):1486-1498(in Chinesewith English abstract).
Hallberg R O,Martinell R. 1976. Vyredox—In situ purification ofground water[J]. Groundwater,14(2):88-93.
Hatch J R,Leventhal J S. 1992. Relationship between inferred redoxpotential of the depositional environment and geochemistry ofthe Upper Pennsylvanian(Missourian)Stark Shale Member ofthe Dennis Limestone,Wabaunsee County,Kansas,USA[J].Chemical Geology,99(1-3):65-82.
He Feng,Lu Baolong,Zhang Zilong,Niu Ting,Huo Zhida,Jia Cui,Yang Mengji. 2019. Metallogenic conditions and prospectingpotential analysis of sandstone-type uranium deposit inHuahai Basin,Hexi Corridor[J]. Uranium Geology,35(5):292-299(in Chinese with English abstract).
He Feng,Ni Shiqi,Niu Ting,Guo Changlin,Zhang Zilong,TianMingming. 2021. Metallogenic pattern of sandstone-typeuranium and prospecting direction of Cretaceous in JiuquanBasin[J]. Uranium Geology,37(3):377-390(in Chinese withEnglish abstract).
He Guangyu,Yang Shufeng,Chen Hanlin,Xiao Ancheng,ChengXiaogan. 2004. New ideas about the Early Cretaceous basinsin western Gansu Corridor and nearby regions[J]. ActaPetrolei Sinica,25(6):18-22(in Chinese with Englishabstract).
Huang Shijie. 1994. Formation conditions and prospecting criteriafor sandstone uranium deposit of interlayered oxidation type[J]. Uranium Geology,10(1):6-13(in Chinese with Englishabstract).
Jones B,Manning D A C. 1994. Comparison of geochemical indicesused for the interpretation of palaeoredox conditions in ancientmudstones[J]. Chemical geology,111(1-4):111-129.
Li Fenqi Wang Chengshan Zhu Lidong Xiang Fang. 2002. Thebasin-range coupling under the regional compressionalregimes:Examples from the Hexi Corridor Basin and NorthQilian Mountains[J]. Sedimentary Geology and TethyanGeology,22(4):17-25(in Chinese with English abstract).
Li Tong. 1994. Elements abundances of China’ s continental crustand its sedimentary layer and upper continental Crust[J].Geochimica,23(2):140-145(in Chinese with Englishabstract).
Li Zhao,Yu Xiaolin,Zhou Wei,Wu Jie. 2024. Geochemicalcharacteristics and sedimentary environment of SaihanFormation sandstone in Naomugeng depression,Erlian Basin[J]. Acta Geologica Sichuan,44(2):306-311,321(in Chinesewith English abstract).
Li Zhuolun,Zhang Naimeng,Wang Naiang,Cheng Hongyi,Li Yu.2014. Lake evolution and its response to climate changeduring the Late Glacial:A record from the Huahai Lake in theHexi Corridor of Northwest China[J]. Journal of DesertResearch,34(2):342-348(in Chinese with English abstract).
Nesbitt H W,Young G M. 1982. Early Proterozoic climates and platemotions inferred from major element chemistry of lutites[J].Nature,299(5885):715-717.
Piper D Z. 1994. Seawater as the source of minor elements in blackshales,phosphorites and other sedimentary rocks[J]. ChemicalGeology,114(1-2):95-114.
Qin Suhua,Wang Xiaoshan,Kang Nanchang,He Baowei,Bai Jun,Pang Xueyan,Duan Xinhong,Wu Zhankui. 2013. An analysisof the effect from Altyn Fault upon Jiuquan Basin[J]. ActaPetrologica Sinica,29(8):2895-2905(in Chinese with Englishabstract).
Roser B P,Korsch R J. 1988. Provenance signatures of sandstone-mudstone suites determined using discriminant functionanalysis of major-element data[J]. Chemical Geology,67(1-2):119-139.
Roser B P,Korsch R J. 1999. Geochemical characterization,evolution and source of a Mesozoic accretionary wedge:theTorlesse terrane,New Zealand[J]. Geological Magazine,136(5):493-512.
Scheffler K,Buehmann D,Schwark L. 2006. Analysis of latePalaeozoic glacial to postglacial sedimentary successions inSouth Africa by geochemical proxies:Response to climateevolution and sedimentary environment[J]. Palaeogeography,Palaeoclimatology,Palaeoecology,240(1-2):184-203.
Taylor G J,Ryan D,Bagby M. 1985. Toward the development of anew self-report alexithymia scale[J]. Psychotherapy andPsychosomatics,44(4):191-199.
Tribovillard N,Algeo T J,Lyons T,Riboulleau A. 2006. Tracemetals as paleoredox and paleoproductivity proxies:Anupdate[J]. Chemical Geology,232(1-2):12-32.
Wu Dehai,Xia Fei,Pan Jiayong,Liu Guoqi,Huang Guolong,LiuWenquan,Wu Jianyong. 2019. Characteristics of hydrothermalalteration and material migration of Mianhuakeng uraniumdeposit in northern Guangdong Province[J]. Acta PetrologicaSinica,35(9):2745-2764(in Chinese with English abstract).
Xiong Guoqing,Wang Jian,Hu Renfa. 2008. Trace elementcharacteristics and sedimentary environment of the Siniansystem of the Fanjingshan area in Guizhou Province[J]. ActaGeoscientica Sinica,29(1):51-60(in Chinese with Englishabstract).
Xue Wei,Xue Chunji,Chi Guoxiang,Peng Yunbiao,Wang Kai.2010. Trace element and REE geochemical characteristics ofsandstone-type uranium deposit in the Dongsheng area of theOrdos Basin, China[J]. Geoscience,24(4):776-784(inChinese with English abstract).
Zhang Jian,Zhang Haihua,Chen Shuwang,Zheng Yuejuan,ZhangDejun,Sun Fei,Huang Xin. 2020. Geochemical characteristicsand geological significance of Upper Permian Linxi Formationin northern Songliao Basin[J]. Journal of Jilin University(Earth Science Edition),50(2):518-530(in Chinese withEnglish abstract).
Zhang Jin,Li Jinyi,Li Yanfeng,Ma Zongjin. 2007. The Cenozoicdeformation of the Alxa Block in central Asia-Question on thenortheastern extension of the Altyn Tagh fault in Cenozoic Time[J]. Acta Geologica Sinica,81(11):1481-1497(in Chinesewith English abstract).
Zhang Jindai. 2004. Summarized analysis on potential of uraniumresources in China and strategy for uranium geologicexploration[J]. Uranium Geology,20(5):260-265(in Chinesewith English abstract).
Zhang Peizhen,Min Wei,Deng Qidong,Mao Fengying. 2003.Paleoearthquakes and recurrence patterns of strongearthquakes in the Haiyuan active fault zone[J]. Science inChina Series D:Earth Sciences,33(8):705-713(in Chinesewith English abstract).
Zhang Tianfu,Sun Lixin,Zhang Yun,Cheng Yinhang,Li Yanfeng,Ma Hailin,Lu Chao,Yang Cai,Guo Genwan. 2016.Geochemical characteristics of the Jurassic Yan’ an andZhiluo Formations in the northern margin of Ordos Basin andtheir paleoenvironmental implications[J]. Acta GeologicaSinica,90(12):3454-3472(in Chinese with English abstract).
Zhang Xinhu. 2007. Study of regional tectonics,metallogenesis andexploration in Gansu Province[D]. Lanzhou:LanzhouUniversity(in Chinese with English abstract).
Zou Xiaobo,Shi Yongqiang,Zheng Yue,Shi Jiyong,Hu Xuetao JiangCaiping,Huang Xiaowei,Xu Yiwei. 2018. Detection ofarginine by AuNPs/CQDs Nanoprobes Based on Fluorescenceresonance energy transfer effect[J]. Chinese Journal ofAnalytical Chemistry,46(6):960-968(in Chinese withEnglish abstract).
(1)王继斌,牛霆,薛栋. 2023.走廊盆地群西部铀矿资源调查评价[R].咸阳:核工业二〇三研究所.
(2)李万华,张甲民. 2006.甘肃省高台县红山地区1:25万砂岩型铀资源区域评价[R].咸阳:核工业二〇三研究所.
基本信息:
中图分类号:P619.14;P534.53
引用信息:
[1]施龙,严兆彬,牛霆,等.花海盆地下白垩统中沟组砂岩地球化学特征及其指示意义[J].铀矿地质,2025,41(06):938-955.
基金信息:
国家自然科学基金项目(编号:42072099); 巴丹吉林盆地及周缘X矿资源调查评价项目(编号:202221); 中核铀业青年创新基金项目(编号:NKLUR-2024-QN-006)联合资助